Her first marriage was to Alfie Karmal. This marital life ended after just two years. She did not have any children in this relationship. She then married Paul in 2003. The couple had a child in 2003. They separated in 2006 and got divorced in 2008.

Mills met Paul in a hotel during the Pride of Britain Award Event in 1999. Mills was awarded the Outstanding bravery award and Paul was present for receiving the award on behalf of his late wife. Mills and Paul talked about charity donation and give her 150 thousand Pounds.

Paul proposed her on a holiday trip by giving her a sapphire and diamond ring which he purchased in India. They got married in 2002, four years after his first partner died of breast cancer. She once said that her life with her husband is really great and Paul is very tidy. He helped her get out of her ‘chocolate’ addiction.

Mills never gave a lot of interviews about her personal life. When asked about it; she said that she wants to guard the privacy of Paul, her child and herself. In 2006, they got separated. Mills accused Paul’s daughter as the reason for their divorce. She tagged her as jealous and evil. Stella, his daughter once stated that she loved her new stepmother and later denied that such a statement was never made.

In a statement during the hearing, Mills said that Paul often smoked, drank and had once stabbed her with a broken wine glass. He also pushed her into a tub when she was pregnant and it caused a miscarriage. Mills proposed a 125 million pound settlement but, Paul offered only 15.8 million pounds. The hearing went for 6 days and at last, Paul settled 16.5 million Pounds. The child support is 35 thousand Pound per annum and the school costs.

The media were very cruel on Mills. They reported that she married him just for his money. Alfie said that Mills is very complicated to live with. He tagged her as a chameleon. He said that he does not hate Mills and just feels sorry for her. He said that the reason for his separation from her was a line of deceit. Miller told Alfie that she had only one boyfriend before him. She said that she knew to drive, but, she did not have a license.

Alfie said that he poured money over Mills for her gifts and her breast cosmetic surgery. She is always drifting and wanted to make a lot of money. Alfie said that Mills lie a lot. She would say that her car was clamped and she paid 90 Pounds. When he called the pound, they would deny it. She would have spent on shopping. She also lived as a mistress and a party girl for an Arab businessman for setting up her modeling contract.